Surface treatment for BSI image sensors

ABSTRACT

A method comprises implanting ions in a substrate to form a plurality of photo diodes, forming an interconnect layer over a first side of the substrate and applying a first halogen treatment process to a second side of the substrate and forming a first silicon-halogen compound layer over the second side of the substrate as a result of applying the first halogen treatment process.

This application is a divisional of U.S. patent application Ser. No.13/728,176, entitled “Surface Treatment for BSI Image Sensors,” filed onDec. 27, 2012, which application is incorporated herein by reference.

BACKGROUND

As technologies evolve, complementary metal-oxide semiconductor (CMOS)image sensors are gaining in popularity over traditional charged-coupleddevices (CCDs) due to certain advantages inherent in the CMOS imagesensors. In particular, a CMOS image sensor may have a high imageacquisition rate, a lower operating voltage, lower power consumption andhigher noise immunity. In addition, CMOS image sensors may be fabricatedon the same high volume wafer processing lines as logic and memorydevices. As a result, a CMOS image chip may comprise both image sensorsand all the necessary logics such as amplifiers, A/D converters and thelike.

CMOS image sensors are pixelated metal oxide semiconductors. A CMOSimage sensor typically comprises an array of light sensitive pictureelements (pixels), each of which may include transistors (switchingtransistor and reset transistor), capacitors, and a photo-sensitiveelement (e.g., a photo-diode). A CMOS image sensor utilizeslight-sensitive CMOS circuitry to convert photons into electrons. Thelight-sensitive CMOS circuitry typically comprises a photo-diode formedin a silicon substrate. As the photo-diode is exposed to light, anelectrical charge is induced in the photo-diode. Each pixel may generateelectrons proportional to the amount of light that falls on the pixelwhen light is incident on the pixel from a subject scene. Furthermore,the electrons are converted into a voltage signal in the pixel andfurther transformed into a digital signal by means of an A/D converter.A plurality of periphery circuits may receive the digital signals andprocess them to display an image of the subject scene.

A CMOS image sensor may comprise a plurality of additional layers suchas dielectric layers and interconnect metal layers formed on top of thesubstrate, wherein the interconnect layers are used to couple the photodiode with peripheral circuitry. The side having additional layers ofthe CMOS image sensor is commonly referred to as a front side, while theside having the substrate is referred to as a backside. Depending on thelight path difference, CMOS image sensors can be further divided intotwo major categories, namely front-side illumination (FSI) image sensorsand backside illumination (BSI) image sensors.

In a FSI image sensor, light from the subject scene is incident on thefront side of the CMOS image sensor, passes through dielectric layersand interconnect layers, and finally falls on the photo diode. Theadditional layers (e.g., opaque and reflective metal layers) in thelight path may limit the amount of light absorbed by the photo diode soas to reduce quantum efficiency. In contrast, there is no obstructionfrom additional layers (e.g., metal layers) in a BSI image sensor. Lightis incident on the backside of the CMOS image sensor. As a result, lightcan strike the photo diode through a direct path. Such a direct pathhelps to increase the number of photons converted into electrons.

BSI image sensors may generate electrons in response to the lightincident on the backside of a CMOS image sensor. However, unwantedcurrent may be generated in the absence of illumination. This unwantedcurrent is known as the dark current. Excessive dark current may causeimage degradation.

BRIEF DESCRIPTION OF THE DRAWINGS

For a more complete understanding of the present disclosure, and theadvantages thereof, reference is now made to the following descriptionstaken in conjunction with the accompanying drawings, in which:

FIG. 1 illustrates a cross sectional view of a backside illuminationimage sensor in accordance with various embodiments of the presentdisclosure;

FIG. 2 illustrates a cross sectional view of a semiconductor substratein accordance with various embodiments of the present disclosure;

FIG. 3 is a cross sectional view of the semiconductor device illustratedin FIG. 2 after a thinning process has been applied to the backside ofthe substrate in accordance with various embodiments of the presentdisclosure;

FIG. 4 is a cross sectional view of the semiconductor device illustratedin FIG. 3 after a halogen treatment process has been applied to thesurface of the backside of the substrate in accordance with variousembodiments of the present disclosure;

FIG. 5 is a cross sectional view of the semiconductor device illustratedin FIG. 4 after an anti-reflection coating (ARC) layer is deposited overthe backside of the substrate in accordance with various embodiments ofthe present disclosure;

FIG. 6 is a cross sectional view of the semiconductor device illustratedin FIG. 5 after a dielectric layer is formed over the ARC layer inaccordance with various embodiments of the present disclosure;

FIG. 7 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 6 after a metal layer is deposited over the backsideillumination film in accordance with various embodiments of the presentdisclosure;

FIG. 8 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 7 after a backside metal grid photolithography process isperformed using a photo resist in accordance with various embodiments ofthe present disclosure; and

FIG. 9 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 8 after an etching process is performed in accordance withvarious embodiments of the present disclosure.

Corresponding numerals and symbols in the different figures generallyrefer to corresponding parts unless otherwise indicated. The figures aredrawn to clearly illustrate the relevant aspects of the variousembodiments and are not necessarily drawn to scale.

DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS

The making and using of the present embodiments are discussed in detailbelow. It should be appreciated, however, that the present disclosureprovides many applicable inventive concepts that can be embodied in awide variety of specific contexts. The specific embodiments discussedare merely illustrative of specific ways to make and use the embodimentsof the disclosure, and do not limit the scope of the disclosure.

The present disclosure will be described with respect to embodiments ina specific context, a halogen surface treatment process for backsideilluminated image sensors. The embodiments of the disclosure may also beapplied, however, to a variety of image sensors. Hereinafter, variousembodiments will be explained in detail with reference to theaccompanying drawings.

FIG. 1 illustrates a cross sectional view of a backside illuminationimage sensor in accordance with various embodiments of the presentdisclosure. The backside illumination image sensor 100 comprises animage sensor pixel array 101, a black level correction region 103 andother regions such as logic circuits, bonding pads and the like. Forsimplicity, the cross sectional view of the backside illumination imagesensor 100 shown in FIG. 1 only illustrates a image sensor pixel array101 and a black level correction region 103.

The image sensor pixel array 101 may comprise a plurality of photodiodes (e.g., photo diodes 107 and 109) formed adjacent to a first sideof a semiconductor substrate 106. Two adjacent photo diodes 107 and 109are separated from each other by an isolation region 111. The photodiodes 107 and 109 are used for generating electrical signals from thesensed light. As shown in FIG. 1, grids 132 and 134 are formed on asecond side of the semiconductor substrate 106. The photo diodes (e.g.,photo diode 107) are formed between two adjacent grids such as grids 132and 134. In other words, two adjacent grids (e.g., grids 132 and 134)define a pixel region of the image sensor pixel array 101. The grids 132and 134 may be formed of a variety of suitable materials such as, forexample, tungsten, aluminum, copper, an alloy or a composite, anycombinations thereof and/or the like.

It should be noted that for simplicity, hereinafter the side havingadditional layers (e.g., the first side) of the backside illuminatedimage sensor 100 is referred to as a front-side of the substrate 106,while the side having grids (e.g., grids 132 and 134) is referred to asa backside of the substrate 106.

The black level correction region 103 may comprise a black referencesensor (not shown), which is used for generating reference black levelsignals. As shown in FIG. 1, the black reference sensor located in theblack level correction region 103 is shielded by a metal shielding layer112. As a result, light does not strike the black reference sensor.Without receiving light, the black reference sensor can provide a blackreference signal for the image sensor pixel array 101. Throughout thedescription, the black level correction region 103 is alternativelyreferred to as the metal shield region 103.

FIG. 1 further illustrates there may be a silicon halogen compound layerformed on the top surface of the substrate 106. More particularly, theremay be a first silicon halogen compound layer 114 formed on a topsurface of the backside of the substrate 106. Likewise, there may be asecond silicon halogen compound layer 116 formed on a front-side surfaceof the substrate 106.

During the fabrication process of backside illumination image sensors, aplurality of dangling bonds may be generated on the top surfaces (e.g.,backside and front-side) of the substrate. Such dangling bonds may causeproblems such as noise, dark currents and/or the like. A silicon halogencompound layer helps to eliminate dangling bonds so that the key devicecharacteristics such as noise and dark currents may be improved. Thedetailed fabrication process of the backside illumination image sensor100 will be described below with respect to FIGS. 2-9.

FIGS. 2-9 illustrate intermediate steps of fabricating the backsideillumination image sensor 100 shown in FIG. 1 in accordance with variousembodiments of the present disclosure. FIG. 2 illustrates a crosssectional view of a semiconductor substrate in accordance with variousembodiments of the present disclosure. The substrate 106 may be of afirst conductivity. In accordance with an embodiment, the substrate 106is a highly doped p-type substrate. The substrate 106 may be formed ofsilicon, germanium, silicon germanium, graded silicon germanium,semiconductor-on-insulator, carbon, quartz, sapphire, glass, or thelike, and may be multi-layered (e.g., strained layers). A lightly dopedp-type epitaxial layer (not shown) may be grown on the highly dopedp-type substrate 106.

The substrate 106 may comprise a plurality of photo active regions. Thephoto active regions may comprise, for example, photo-diodes (e.g.,photo active region 107) formed by implanting impurity ions into theepitaxial layer. Furthermore, the photo active regions may be a PNjunction photo-diode, a PNP photo-transistor, an NPN photo-transistorand/or the like. In accordance with an embodiment, the photo activeregions such as photo active region may comprise a p-type layer formedon an n-type region, wherein the n-type region is formed on an epitaxiallayer grown from a p-type semiconductor substrate (e.g., highly dopedp-type substrate 106).

In accordance with an embodiment, n-type impurity ions are implantedinto the p-type epitaxial layer to form an n-type photo diode region(not shown). In addition, p-type impurity ions are implanted into then-type photo diode region to form a p-type diode region (not shown). Then-type photo diode region and the p-type photo diode region further forma photo diode region (e.g., photo diodes 107 and 109).

The substrate 106 may comprise a plurality of pixels, each of whichcomprises a photo diode region (e.g., photo diode 107). In order toprevent crosstalk between adjacent pixels, an isolation region 111 isemployed to separate two adjacent photo diodes. In accordance with someembodiments, the isolation region 111 may be a shallow trench isolation(STI) structure. The STI structure may be formed by etching a portion ofthe substrate 106 to form a trench and filling the trench with oxideand/or other dielectric materials.

A dielectric layer 104 is typically formed over the front-side of thesubstrate 106. In accordance with an embodiment, the dielectric layer104 may be formed of low-K dielectric materials such as silicon oxide,borophosphosilicate glass (BPSG), phosphosilicate glass (PSG),fluorinated silicate glass (FSG), carbon-doped silicon oxide or thelike. The dielectric layer 104 may be formed by any suitable techniquessuch as chemical vapor deposition (CVD) techniques or the like.

A metal interconnect layer 102 may be formed over the dielectric layer104. The metal interconnect layer 102 may comprise a plurality of metallines 120. The metal interconnect layer 102 can be patterned by plasmaetching or a damascene process and may be formed of any conductivematerial suitable for the particular application. Materials that may besuitable include, for example, aluminum, copper, doped polysilicon orthe like. Contacts and vias (not shown) may be formed to provideelectrical connectivity between the metal interconnect layer 102 andunderlying circuitry (not shown).

FIG. 2 further illustrates a silicon-halogen compound layer 116 may beformed on the front-side surface of the substrate 106. The process ofgenerating the silicon-halogen compound layer 116 is the same as theprocess of generating the silicon-halogen compound layer 114 (not shownbut illustrated in FIG. 1). The detailed process of generating a siliconhalogen compound layer on the top surface of a substrate will bedescribed below in detail with respect to FIG. 4.

FIG. 3 is a cross sectional view of the semiconductor device illustratedin FIG. 2 after a thinning process has been applied to the backside ofthe substrate in accordance with various embodiments of the presentdisclosure. The substrate 106 prior to a thinning process is of athickness in a range from about 700 um to about 800 um. According to thefabrication processes of backside illuminated image sensors, thebackside of the substrate 106 is thinned until the highly doped p-typesubstrate 106 is removed and the lightly doped p-type epitaxial layer isexposed.

In some embodiments, the backside of the substrate 106 of the backsideilluminated image sensor 100 may be thinned to a thickness in a rangefrom about 3 um to about 4 um. Such a thin substrate layer allows lightto pass through the substrate and hit photo diodes (e.g., photo diodes107 and 109) embedded in the substrate 106 without being absorbed by thesubstrate. The thinning process may be implemented by using suitabletechniques such as grinding, polishing, chemical etching and/or thelike.

FIG. 4 is a cross sectional view of the semiconductor device illustratedin FIG. 3 after a halogen treatment process has been applied to thesurface of the backside of the substrate in accordance with variousembodiments of the present disclosure. In some embodiments, the halogentreatment process is implemented using a dry halogen treatment. Inparticular, the semiconductor device is placed in a chamber and ahalogen gas flows over the surface of the backside of the semiconductordevice. The halogen gas may comprise fluorine. Fluorine containing gasmay react with the silicon surface of the semiconductor device toproduce the silicon halogen compound layer 114.

The percentage of fluorine on the top surface of the backside of thesubstrate 106 is in a range from about 0.15% to about 0.5%. Thetemperature of the dry halogen treatment may be in a range from about250 degrees to about 450 degrees.

It should be noted that the halogen gas may be replaced by a plasmaenhanced process. The chamber may be configured to generate plasma usingthe gas in the chamber. During the plasma enhanced treatment, thedangling bonds on the top surface of the backside of the semiconductordevices are replaced by stronger bonds generated by the plasma enhancedtreatment.

In alternative embodiments, the halogen treatment process is implementedusing a wet halogen treatment. In particular, the backside surface ofthe semiconductor device is exposed to suitable fluorine containingacids such as hydrofluoric acid (HF) and the like. The fluorinecontaining acid may react with the silicon surface of the semiconductordevice to produce the silicon halogen compound layer 114. The durationof the wet halogen treatment is in a range from about 10 seconds toabout 20 seconds.

FIG. 5 is a cross sectional view of the semiconductor device illustratedin FIG. 4 after an anti-reflection coating (ARC) layer is deposited overthe backside of the substrate in accordance with various embodiments ofthe present disclosure. Once the silicon halogen compound layer 114 isformed on the top surface of the backside of the substrate 106, the ARClayer 108 is formed over the backside of the substrate 106 subsequently.

The ARC layer 108 may be formed of a nitride material, an organicmaterial, an oxide material and the like. The ARC layer 108 may beformed using suitable techniques such as CVD and the like.

FIG. 6 is a cross sectional view of the semiconductor device illustratedin FIG. 5 after a dielectric layer is formed over the ARC layer inaccordance with various embodiments of the present disclosure. Thedielectric layer 110 may be formed of oxide. More particularly, thedielectric layer 110 may comprise a first oxide layer, a second oxidelayer and a buffer oxide layer (not shown respectively).

In some embodiments, the first oxide layer is a plasma enhanced oxide(PEOX) having a thickness of about 1100 Angstroms. In some embodiments,the second oxide layer is a low deposited rate resistor protection oxide(LRPO) having a thickness of about 4200 Angstroms. In some embodiments,the buffer oxide layer is a plasma enhanced oxide (PEOX) having athickness of about 500 Angstroms. As such, the dielectric layer 110 isof a collective thickness of about 5800 Angstroms. It should be notedthat, throughout the description, the ARC layer 108 and the dielectriclayer 110 may be collectively referred to as a backside illuminationfilm.

FIG. 7 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 6 after a metal layer is deposited over the backsideillumination film in accordance with various embodiments of the presentdisclosure. The metal layer 702 is formed over the dielectric layer 110.In accordance with an embodiment, the metal materials deposited over thedielectric layer 110 include copper, aluminum, tantalum, titaniumnitride, any combinations thereof and/or the like. In some embodiments,the metal layer 702 is of a thickness in a range from about 50 nm toabout 200 nm.

In accordance with an embodiment, the metal materials may be depositedover the backside of the substrate 106 using a suitable depositionprocess such as CVD, plasma enhanced CVD (PECVD), atomic layerdeposition (ALD), electroplating and/or the like.

FIG. 8 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 7 after a backside metal grid photolithography process isperformed using a photo resist in accordance with various embodiments ofthe present disclosure. A photoresist material is deposited on the metallayer 702 to form a photo resist layer 802. According to the locationand shape of the grids and metal shielding layer shown in FIG. 1,portions of the photo resist layer 802 are exposed. The patterningprocess shown in FIG. 8 is well known, and hence is not discussed infurther detail.

FIG. 9 illustrates a cross sectional view of the semiconductor deviceshown in FIG. 8 after an etching process is performed in accordance withvarious embodiments of the present disclosure. An etching process, suchas an anisotropic dry etch process, may be used to remove portions ofthe metal layer 702 to form the grids 132, 134 and the metal shieldinglayer 112.

In accordance with an embodiment, an apparatus comprises an image sensorformed adjacent to a first side of a semiconductor substrate, wherein afirst dielectric layer formed over the first side of the semiconductorsubstrate, and an interconnect layer formed over the first dielectriclayer, a backside illumination film formed over a second side of thesemiconductor substrate and a first silicon halogen compound layerformed between the second side of the semiconductor substrate and thebackside illumination film.

In accordance with another embodiment, a method comprises forming animage sensor adjacent to a first side of a substrate, thinning a secondside of the substrate, performing a halogen treatment on the second sideof the substrate and forming a backside illumination layer on a secondside of the substrate.

In accordance with yet another embodiment, a device comprises an arrayof photo diodes, each of which is formed adjacent to a first side of asemiconductor substrate, a plurality of isolation regions, each of whichis formed between two adjacent photo diodes, a first silicon halogencompound layer formed over a top surface of a second side of thesemiconductor substrate, an anti-reflection coating layer formed on thefirst silicon halogen compound layer and a dielectric layer formed onthe anti-reflection coating layer.

Although embodiments of the present disclosure and its advantages havebeen described in detail, it should be understood that various changes,substitutions and alterations can be made herein without departing fromthe spirit and scope of the disclosure as defined by the appendedclaims.

Moreover, the scope of the present application is not intended to belimited to the particular embodiments of the process, machine,manufacture, composition of matter, means, methods and steps describedin the specification. As one of ordinary skill in the art will readilyappreciate from the present disclosure, processes, machines,manufacture, compositions of matter, means, methods, or steps, presentlyexisting or later to be developed, that perform substantially the samefunction or achieve substantially the same result as the correspondingembodiments described herein may be utilized according to the presentdisclosure. Accordingly, the appended claims are intended to includewithin their scope such processes, machines, manufacture, compositionsof matter, means, methods, or steps.

What is claimed is:
 1. A method comprising: implanting ions in a substrate to form a plurality of photo diodes; forming an interconnect layer over a first side of the substrate; and applying a first halogen treatment process to a second side of the substrate and forming a first silicon-halogen compound layer over the second side of the substrate as a result of applying the first halogen treatment process to the substrate, and applying a second halogen treatment process to the first side of the substrate and forming a second silicon-halogen compound layer over the first side of the substrate as a result of applying the second halogen treatment process.
 2. The method of claim 1, wherein: the substrate comprises an image sensor region and a black level correction region, and wherein the black level correction region is shielded by a metal shielding layer deposited over the second side of the substrate.
 3. The method of claim 1, further comprising: depositing an anti-reflection coating layer formed over the second side of the substrate; and depositing a dielectric layer over the anti-reflection coating layer.
 4. The method of claim 1, further comprising: prior to the step of applying the first halogen treatment process to the second side of the substrate, thinning the second side of the substrate to a thickness in a range from about 3 um to about 4 um.
 5. The method of claim 1, wherein: two adjacent photo diodes are separated by an isolation region.
 6. The method of claim 1, further comprising: depositing a metal layer over the second side of the substrate; and applying an etching process to the metal layer and forming a metal shielding layer and a plurality of grids as a result of applying the etching process.
 7. A method comprising: forming a plurality of photo diodes in a substrate; forming an interconnect layer over a first side of the substrate; applying a second halogen treatment process to the first side of the substrate and forming a first silicon-halogen compound layer over the first side of the substrate as a result of applying the second halogen treatment process; and applying a first halogen treatment process to a second side of the substrate and forming a second silicon-halogen compound layer over the second side of the substrate as a result of applying the first halogen treatment process.
 8. The method of claim 7, further comprising: forming a metal shielding layer over the second side of the substrate, wherein the metal shielding layer is over a black level correction region of the substrate, and wherein the black level correction region is adjacent to the plurality of photo diodes.
 9. The method of claim 7, further comprising: prior to the step of applying the first halogen treatment process to the second side of the substrate, thinning the second side of the substrate.
 10. The method of claim 9, wherein: the substrate is thinned to a thickness in a range from about 3 um to about 4 um.
 11. The method of claim 7, further comprising: depositing a first plasma enhanced oxide layer over the second side of the substrate; depositing a low deposited rate resistor protection oxide layer over the first plasma enhanced oxide layer; and depositing a second plasma enhanced oxide layer over the low deposited rate resistor protection oxide layer.
 12. The method of claim 7, further comprising: growing an epitaxial layer on the substrate; and implanting ions in the epitaxial layer to form the plurality of photo diodes.
 13. The method of claim 1, wherein: two adjacent photo diodes of the plurality of photo diodes are separated from each other by an isolation region.
 14. A method comprising: forming an image sensor adjacent to a first side of a substrate; thinning a second side of the substrate; after the step of thinning the second side of the substrate, performing a first halogen treatment on the second side of the substrate and performing a second halogen treatment process on the first side of the substrate; and forming a backside illumination layer on the second side of the substrate.
 15. The method of claim 14, further comprising: depositing an anti-reflection coating layer on the second side of the substrate; and depositing a dielectric layer on the anti-reflection coating layer.
 16. The method of claim 14, further comprising: forming a metal layer over the backside illumination layer; and patterning the metal layer to form a metal shielding layer and a plurality of grids.
 17. The method of claim 14, wherein forming the image sensor includes: growing an epitaxial layer on the substrate; and implanting ions in the epitaxial layer to form the image sensor.
 18. The method of claim 17, wherein forming the image sensor further includes: forming an isolation region in the epitaxial layer, wherein the isolation region encloses the image sensor.
 19. The method of claim 17, wherein forming the image sensor includes: forming an n-type photo diode region of the image sensor by implanting n-type ions in the epitaxial layer; and forming a p-type photo diode region of the image sensor by implanting p-type ions in the epitaxial layer, wherein the n-type photo diode region and the p-type photo diode region form a photo diode region.
 20. The method of claim 14, wherein thinning the second side of the substrate includes: thinning the substrate until the substrate is of a thickness in a range from about 3 um to about 4 um. 